Chemicals Used in Dry-cleaning Operations

Oct 5, 2018

Environmental Enlightenment #090

(Acknowledgement: http://www.drycleancoalition.org)

Dry-cleaning is the washing of fabrics in non-aqueous solvents.

The first regular use of a non-aqueous solvent in garment cleaning was in 1716, when spirits of turpentine were used to remove grease and oil stains.

The dry-cleaning industry was established in Europe in the first half of the nineteenth century. The most widely used solvents in early dry-cleaning operations were petroleum based and included petroleum naphtha, benzene, kerosene, and white gasoline.

White gasoline was the predominant dry-cleaning solvent in the United States from the late nineteenth century until the early 1920s. Due to the high volatility of these petroleum solvents, fires and explosions were major hazards associated with dry-cleaning operations.

Acknowledgment: Butch Cassidy and the Sundance Kid (1969)

In 1924, an Atlanta drycleaner named W. J. Stoddard worked with Lloyd E. Jackson of the Mellon Research Institute to develop specifications for a less volatile petroleum dry-cleaning solvent that became known as Stoddard solvent.

(Alamy.com: Stella Court Treatt, née Hinds, (1895 -1976) with her husband Major Chaplin Court Treatt, (1888-1954) on her left and her brother Errol Hinds, (1908 – 1980) on her right during their Court Treatt expedition, the first successful trip by ‘road’ from Cape Town to Cairo in 1924, using two Crossley cars.)

Drycleaners began using Stoddard solvent in 1928 and it was the predominant dry-cleaning solvent in the United States from the late 1920s until the late 1950s.

Since the introduction of Stoddard solvent, the industry trend has been towards the development of petroleum dry-cleaning solvents of lesser flammability.

One of the problems associated with petroleum dry-cleaning solvents is biodegradation

Bacteria enters the dry-cleaning system through the clothing or in water introduced into the system, they feed on the petroleum solvent and degrade the petroleum compounds producing a “sour” odor. Once the solvent has degraded, it must be discarded.

To combat this problem, bactericides or biocides are added to the system, normally in detergents.

The first chlorinated solvent utilized in dry-cleaning operations was carbon tetrachloride, which was used as a dry-cleaning solvent in the United States from the 1920s until the early 1950s. Carbon tetrachloride was commonly blended with other solvents. Because of its high toxicity and tendency to corrode equipment, carbon tetrachloride is no longer used as a dry-cleaning solvent.

In 1930, trichloroethylene (TCE) was introduced as a dry-cleaning solvent in the United States. TCE causes bleeding of some dyes and therefore, it is no longer used as a primary dry-cleaning solvent.

In 1934, perchloroethylene (PCE) was introduced as a dry-cleaning solvent in the United States. The superior cleaning ability of PCE, coupled with petroleum shortages during World War II and municipal fire codes prohibiting the use of petroleum solvents resulted in increased use of PCE.

By the early 1960s, PCE became the predominant dry-cleaning solvent in the United States.

PCE is toxic. Studies of people exposed in the workplace have found associations with several types of cancer including bladder cancer, non-Hodgkin lymphoma, multiple myeloma. EPA has classified tetrachloroethylene as likely to be carcinogenic to humans.

(Ref. https://www.epa.gov/sites/production/files/2016-09/documents/tetrachloroethylene.pdf)

Prior to being dry-cleaned, heavily stained garments are usually pre-cleaned or “pre-spotted” using a wide variety of chemicals. Spot cleaning is also performed after the clothes are dry-cleaned and stains still remain on the clothing.

Dry-side spotting agents used to include some of the most toxic chemicals used in dry-cleaning operations.

Armen Cleaners – Wool Spotting Department, March 1949
Courtesy of The Ann Arbor District Library. www.aadl.org

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